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C–H arylation of triphenylene, naphthalene and related arenes using Pd/C

A highly selective arylation of a number of polyaromatic hydrocarbons (PAHs) with aryliodonium salts and Pd/C as the only reagent is reported. The first C–H functionalization of triphenylene is explored, and proceeds at the most sterically hindered position. This non-chelate assisted C–H functionali...

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Publicado en:Chem Sci
Main Authors: Collins, Karl D., Honeker, Roman, Vásquez-Céspedes, Suhelen, Tang, Dan-Tam D., Glorius, Frank
Formato: Artigo
Idioma:Inglês
Publicado: Royal Society of Chemistry 2015
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC5649329/
https://ncbi.nlm.nih.gov/pubmed/29308135
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4sc03051f
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