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Synthesis and reactivity of cyclo-tetra(stibinophosphonium) tetracations: redox and coordination chemistry of phosphine–antimony complexes
Reductive elimination of [R(3)PPR(3)](2+), [11(R)](2+), from the highly electrophilic Sb(III) centres in [(R(3)P)(3)Sb](3+), [8(R)](3+), gives Sb(I) containing cations [(R(3)P)Sb](1+), [9(R)](1+), which assemble into frameworks identified as cyclo-tetra(stibinophosphonium) tetracations, [(R(3)P)(4)S...
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Publicado no: | Chem Sci |
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Main Authors: | , , , , |
Formato: | Artigo |
Idioma: | Inglês |
Publicado em: |
Royal Society of Chemistry
2015
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Assuntos: | |
Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5647858/ https://ncbi.nlm.nih.gov/pubmed/29308163 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4sc03939d |
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