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Extending N-heterocyclic carbene ligands into the third dimension: a new type of hybrid phosphazane/NHC system

A simple, “click” synthetic approach to a new type of hybrid phosph(III)azane/NHC system is described. The presence of the phosphazane P(2)N(2) ring unit, with P atoms flanking the NCN fragment and with this ring perpendicular to the binding site of the NHC, provides unique opportunities for modifyi...

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Détails bibliographiques
Publié dans:Chem Sci
Auteurs principaux: Roth, Torsten, Vasilenko, Vladislav, Benson, Callum G. M., Wadepohl, Hubert, Wright, Dominic S., Gade, Lutz H.
Format: Artigo
Langue:Inglês
Publié: Royal Society of Chemistry 2015
Sujets:
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC5647813/
https://ncbi.nlm.nih.gov/pubmed/29308160
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4sc03966a
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