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Chemoselective Reductions of Phosphine Oxides by 1,3-Diphenyl-Disiloxane

Reduction of phosphine oxides to the corresponding phosphine represents the most straightforward method to prepare these valuable reagents. However, existing methods to reduce phosphine oxides suffer from inadequate chemoselectivity due to the strength of the P=O bond and/or poor atom economy. Herei...

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Publicado en:Chemistry
Main Authors: Buonomo, Joseph A., Eiden, Carter G., Aldrich, Courtney C.
Formato: Artigo
Idioma:Inglês
Publicado: 2017
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC5647249/
https://ncbi.nlm.nih.gov/pubmed/28840623
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201703875
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