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Self-assembled trinuclear arsenic and antimony macrobicycles

The synthesis of six trinuclear Pn(3)L(2) macrobicycles (Pn = As, Sb) was achieved by self-assembly of a pnictogen trichloride and a 2,4,6-trisubstituted-1,3,5-benzenetrimethanethiol ligand. (1)H-NMR spectroscopy reveals self-assembly in 1,1,2,2-tetrachloroethane is dynamic in solution producing two...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Collins, Mary S., Choi, Robert Y., Zakharov, Lev N., Watson, Lori A., Hay, Benjamin P., Johnson, Darren W.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5646260/
https://ncbi.nlm.nih.gov/pubmed/29308156
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4sc04042b
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