Exploiting parameter space in MOFs: a 20-fold enhancement of phosphate-ester hydrolysis with UiO-66-NH(2)

The hydrolysis of nerve agents is of primary concern due to the severe toxicity of these agents. Using a MOF-based catalyst (UiO-66), we have previously demonstrated that the hydrolysis can occur with relatively fast half-lives of 50 minutes. However, these rates are still prohibitively slow to be e...

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Udgivet i:Chem Sci
Main Authors: Katz, Michael J., Moon, Su-Young, Mondloch, Joseph E., Beyzavi, M. Hassan, Stephenson, Casey J., Hupp, Joseph T., Farha, Omar K.
Format: Artigo
Sprog:Inglês
Udgivet: Royal Society of Chemistry 2015
Fag:
Chemistry
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5645779/
https://ncbi.nlm.nih.gov/pubmed/29308142
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c4sc03613a
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