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Mechanistic Kinetic Modeling of Thiol–Michael Addition Photopolymerizations via Photocaged “Superbase” Generators: An Analytical Approach
A kinetic mechanism and the accompanying mathematical framework are presented for base-mediated thiol–Michael photopolymerization kinetics involving a photobase generator. Here, model kinetic predictions demonstrate excellent agreement with a representative experimental system composed of 2-(2-nitro...
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| Publicado no: | Macromolecules |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5630186/ https://ncbi.nlm.nih.gov/pubmed/28989189 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.macromol.6b01605 |
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