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The Role of Rydberg–Valence Coupling in the Ultrafast Relaxation Dynamics of Acetone

[Image: see text] The electronic structure of excited states of acetone is represented by a Rydberg manifold that is coupled to valence states which provide very fast and efficient relaxation pathways. We observe and characterize the transfer of population from photoexcited Rydberg states (6p, 6d, 7...

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Detalhes bibliográficos
Publicado no:J Phys Chem A
Main Authors: Koch, Markus, Thaler, Bernhard, Heim, Pascal, Ernst, Wolfgang E.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2017
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5608382/
https://ncbi.nlm.nih.gov/pubmed/28737942
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.jpca.7b05012
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