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Limiting Values of the one-bond C–H Spin-Spin Coupling Constants of the Imidazole Ring of Histidine at High-pH
Assessment of the relative amounts of the forms of the imidazole ring of Histidine (His), namely the protonated (H(+)) and the tautomeric N(ε2)-H and N(δ1)-H forms, respectively, is a challenging task in NMR spectroscopy. Indeed, their determination by direct observation of the (15)N and (13)C chemi...
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| 發表在: | J Mol Struct |
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| Main Authors: | , |
| 格式: | Artigo |
| 語言: | Inglês |
| 出版: |
2017
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| 主題: | |
| 在線閱讀: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5596661/ https://ncbi.nlm.nih.gov/pubmed/28919647 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.molstruc.2017.01.022 |
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