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Assessing the fractions of tautomeric forms of the imidazole ring of histidine in proteins as a function of pH

A method is proposed to determine the fraction of the tautomeric forms of the imidazole ring of histidine in proteins as a function of pH, provided that the observed [Image: see text] and [Image: see text] chemical shifts and the protein structure, or the fraction of H(+) form, are known. This metho...

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Detalhes bibliográficos
Main Authors: Vila, Jorge A., Arnautova, Yelena A., Vorobjev, Yury, Scheraga, Harold A.
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2011
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3078339/
https://ncbi.nlm.nih.gov/pubmed/21422292
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1102373108
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