Pseudosymmetry and high Z′ structures: the case of rac-(2R,2′R,5′S)-2-methyl-5′-[(1R,2R,5S,5′S)-1,4,4,5′-tetra­methyl­dihydro-3′H-3,8-dioxa­spiro­[bi­cyclo­[3.2.1]octane-2,2′-furan]-5′-yl]-3,4,1′,2′,3′,4′-hexa­hydro-[2,2′-bi­furan]-5(2H)-one

The title compound, C(22)H(34)O(6), is one of the products obtained by oxidation of squalene with the catalytic system RuO(4)(cat.)/NaIO(4). It crystallizes in the P-1 space group, with four crystallographically independent mol­ecules related by a pseudo-C (2) symmetry axis. The structural analysis...

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Veröffentlicht in:Acta Crystallogr E Crystallogr Commun
Hauptverfasser: Piccialli, Vincenzo, Tuzi, Angela, Centore, Roberto
Format: Artigo
Sprache:Inglês
Veröffentlicht: International Union of Crystallography 2017
Schlagworte:
Research Communications
Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5588561/
https://ncbi.nlm.nih.gov/pubmed/28932455
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S2056989017010805
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