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Cu/Mn bimetallic catalysis enables carbonylative Suzuki–Miyaura coupling with unactivated alkyl electrophiles

A bimetallic system consisting of Cu-carbene and Mn-carbonyl co-catalysts was employed for carbonylative C–C coupling of arylboronic esters with alkyl halides, allowing for the convergent synthesis of ketones. The system operates under mild conditions and exhibits complementary reactivity to Pd cata...

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Detaylı Bibliyografya
Yayımlandı:Chem Sci
Asıl Yazarlar: Pye, Dominic R., Cheng, Li-Jie, Mankad, Neal P.
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: Royal Society of Chemistry 2017
Konular:
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC5585854/
https://ncbi.nlm.nih.gov/pubmed/28966784
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc01170a
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