Equilibrium and ultrafast kinetic studies manipulating electron transfer: A short-lived flavin semiquinone is not sufficient for electron bifurcation

Flavin-based electron transfer bifurcation is emerging as a fundamental and powerful mechanism for conservation and deployment of electrochemical energy in enzymatic systems. In this process, a pair of electrons is acquired at intermediate reduction potential (i.e. intermediate reducing power), and...

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Udgivet i:J Biol Chem
Main Authors: Hoben, John P., Lubner, Carolyn E., Ratzloff, Michael W., Schut, Gerrit J., Nguyen, Diep M. N., Hempel, Karl W., Adams, Michael W. W., King, Paul W., Miller, Anne-Frances
Format: Artigo
Sprog:Inglês
Udgivet: American Society for Biochemistry and Molecular Biology 2017
Fag:
Bioenergetics
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5572931/
https://ncbi.nlm.nih.gov/pubmed/28615449
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1074/jbc.M117.794214
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