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Hg(OTf)(2) Catalyzed Intramolecular 1,4-Addition of Donor–Acceptor Cyclopropenes to Arenes

A Hg(OTf)(2) catalyzed intramolecular arene 1,4-addition reaction of N-benzyl donor–acceptor cyclo-propenecarboxamides was developed to synthesize a series of [3.2.2]nonatriene derivatives. This novel reaction is also observed with silver(I) catalysts known to form metal carbene intermediates in com...

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Publicat a:Org Lett
Autors principals: Deng, Yongming, Jing, Changcheng, Zavalij, Peter Y., Doyle, Michael P.
Format: Artigo
Idioma:Inglês
Publicat: 2015
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5572213/
https://ncbi.nlm.nih.gov/pubmed/26295847
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.5b02129
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