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Mild and Regioselective Pd(OAc)(2)-Catalyzed C–H Arylation of Tryptophans by [ArN(2)]X, Promoted by Tosic Acid
[Image: see text] A regioselective Pd-mediated C–H bond arylation methodology for tryptophans, utilizing stable aryldiazonium salts, affords C2-arylated tryptophan derivatives, in several cases quantitatively. The reactions proceed in air, without base, and at room temperature in EtOAc. The syntheti...
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| Publicado no: | ACS Catal |
|---|---|
| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American
Chemical Society
2017
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| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5557615/ https://ncbi.nlm.nih.gov/pubmed/28824821 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.6b03121 |
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