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Base-promoted isomerization of CF(3)-containing allylic alcohols to the corresponding saturated ketones under metal-free conditions
Following to the computational expectation, our previously reported intriguing 1,3-proton shift of 4,4,4-trifluorobut-2-yn-1-ols was successfully extended to the 4,4,4-trifluorobut-2-en-1-ol system under metal-free conditions to afford the corresponding saturated ketones in high to excellent chemica...
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| Publicado no: | Beilstein J Org Chem |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Beilstein-Institut
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5550803/ https://ncbi.nlm.nih.gov/pubmed/28845194 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.13.149 |
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