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Phenylsilane as an effective desulfinylation reagent

The reduction using phenylsilane in a KOH-catalyzed system was applied successfully to the conversion of sulfinyl-substituted cyclopropylcarboxylates into the corresponding alcohols. The presence of sulfinyl substituents in the α-position to the carboxylate group caused a desulfinylation product for...

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Detalhes bibliográficos
Publicado no:Beilstein J Org Chem
Main Authors: Midura, Wanda H, Rzewnicka, Aneta, Krysiak, Jerzy A
Formato: Artigo
Idioma:Inglês
Publicado em: Beilstein-Institut 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5550773/
https://ncbi.nlm.nih.gov/pubmed/28845195
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.13.150
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