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Correlating the para-substituent effects on Ru(II)-polypyridine photophysical properties and on the corresponding hybrid P450 BM3 enzymes photocatalytic activity

Ru(II)-diimine complexes covalently attached near the heme active site of P450 BM3 enzymes have been used to rapidly inject electrons and drive selective C-H functionalization upon visible light irradiation. Herein, we have generated a series of hybrid P450 BM3 enzymes containing a photosensitizer o...

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Detalhes bibliográficos
Publicado no:Inorg Chem
Main Authors: Shalan, Hadil, Colbert, Alexander, Nguyen, Thanh Truc, Kato, Mallory, Cheruzel, Lionel
Formato: Artigo
Idioma:Inglês
Publicado em: 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5535733/
https://ncbi.nlm.nih.gov/pubmed/28537742
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.7b00685
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