Bimetallic iron–iron and iron–zinc complexes of the redox-active ONO pincer ligand

A new bimetallic platform comprising a six-coordinate Fe(ONO)(2) unit bound to an (ONO)M (M = Fe, Zn) has been discovered ((ONO(cat))H(3) = bis(3,5-di-tert-butyl-2-phenol)amine). Reaction of Fe(ONO)(2) with either (ONO(cat))Fe(py)(3) or with (ONO(q))FeCl(2) under reducing conditions led to the forma...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Wong, Janice L., Higgins, Robert F., Bhowmick, Indrani, Cao, David Xi, Szigethy, Géza, Ziller, Joseph W., Shores, Matthew P., Heyduk, Alan F.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2016
Assuntos:
Chemistry
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5530940/
https://ncbi.nlm.nih.gov/pubmed/28808535
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc03006d
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