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Taming the beast: fluoromesityl groups induce a dramatic stability enhancement in boroles
The electron-deficient pentaarylborole 1-(2′,4′,6′-tris(trifluoromethyl)phenyl)-2,3,4,5-tetraphenylborole (1) has been synthesised with the long-term aim of developing borole-based optoelectronic materials. The bulky 2,4,6-tris(trifluoromethyl)phenyl (FMes) group on the boron atom of 1 significantly...
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| Publicado en: | Chem Sci |
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| Autores principales: | , , , , , , , , , , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
Royal Society of Chemistry
2015
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5523080/ https://ncbi.nlm.nih.gov/pubmed/28791091 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc02205c |
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