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Activation of Dinitrogen as A Dipolarophile in 1,3-Dipolar Cycloadditions: A Theoretical Study Using Nitrile Imines as “Octet” 1,3-Dipoles

Theoretical calculations at the G4MP2 level of theory demonstrate that it is possible to activate dinitrogen to make it react in dipolar cycloadditions using neutral beryllium derivatives and other neutral metallic compounds. For the particular case of beryllium, the barrier decreases more than 40 k...

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Библиографические подробности
Опубликовано в: :Sci Rep
Главные авторы: Montero-Campillo, M. Merced, Alkorta, Ibon, Elguero, José
Формат: Artigo
Язык:Inglês
Опубликовано: Nature Publishing Group UK 2017
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Online-ссылка:https://ncbi.nlm.nih.gov/pmc/articles/PMC5522451/
https://ncbi.nlm.nih.gov/pubmed/28733626
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41598-017-05708-z
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