Persistent four-coordinate iron-centered radical stabilized by π-donation

Dinuclear iron carbonyl complex 2, which contains an elongated unsupported Fe–Fe bond, was synthesized by the reaction between Fe(2)(CO)(9) and phosphinyl radical 1. Thermal Fe–Fe bond homolysis led to the generation of a four-coordinate carbonyl-based iron-centered radical, 3, which is stabilized b...

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Publicat a:Chem Sci
Autors principals: Sunada, Yusuke, Ishida, Shintaro, Hirakawa, Fumiya, Shiota, Yoshihito, Yoshizawa, Kazunari, Kanegawa, Shinji, Sato, Osamu, Nagashima, Hideo, Iwamoto, Takeaki
Format: Artigo
Idioma:Inglês
Publicat: Royal Society of Chemistry 2016
Matèries:
Chemistry
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5515065/
https://ncbi.nlm.nih.gov/pubmed/28758000
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc02601f
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