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Au(I)Cl-bound N-heterocyclic carbene ligands form MII4(LAuCl)(6) integrally gilded cages

The incorporation of an N-heterocyclic carbene (NHC) moiety into a self-assembled MII4L(6) cage framework required the NHC first to be metallated with gold(i). Bimetallic cages could then be constructed using zinc(ii) and cadmium(ii) templates, showing weak luminescence. The cages were destroyed by...

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書誌詳細
出版年:Chem Sci
主要な著者: Ramsay, William J., Foster, Jonathan A., Moore, Katharine L., Ronson, Tanya K., Mirgalet, Raphaël J., Jefferson, David A., Nitschke, Jonathan R.
フォーマット: Artigo
言語:Inglês
出版事項: Royal Society of Chemistry 2015
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC5512534/
https://ncbi.nlm.nih.gov/pubmed/28757991
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc03065j
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