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Au(I)Cl-bound N-heterocyclic carbene ligands form MII4(LAuCl)(6) integrally gilded cages
The incorporation of an N-heterocyclic carbene (NHC) moiety into a self-assembled MII4L(6) cage framework required the NHC first to be metallated with gold(i). Bimetallic cages could then be constructed using zinc(ii) and cadmium(ii) templates, showing weak luminescence. The cages were destroyed by...
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出版年: | Chem Sci |
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主要な著者: | , , , , , , |
フォーマット: | Artigo |
言語: | Inglês |
出版事項: |
Royal Society of Chemistry
2015
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主題: | |
オンライン・アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5512534/ https://ncbi.nlm.nih.gov/pubmed/28757991 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc03065j |
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