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Stereoelectronic source of the anomalous stability of bis-peroxides
The unusual stability of bis- and tris-peroxides contradicts the conventional wisdom – some of them can melt without decomposition at temperatures exceeding 100 °C. In this work, we disclose a stabilizing stereoelectronic effect that two peroxide groups can exert on each other. This stabilization or...
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| Vydáno v: | Chem Sci |
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| Hlavní autoři: | , , , |
| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
Royal Society of Chemistry
2015
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5508698/ https://ncbi.nlm.nih.gov/pubmed/28757970 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc02402a |
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