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Stereoelectronic source of the anomalous stability of bis-peroxides

The unusual stability of bis- and tris-peroxides contradicts the conventional wisdom – some of them can melt without decomposition at temperatures exceeding 100 °C. In this work, we disclose a stabilizing stereoelectronic effect that two peroxide groups can exert on each other. This stabilization or...

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Publicat a:Chem Sci
Autors principals: Gomes, Gabriel dos Passos, Vil', Vera, Terent'ev, Alexander, Alabugin, Igor V.
Format: Artigo
Idioma:Inglês
Publicat: Royal Society of Chemistry 2015
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5508698/
https://ncbi.nlm.nih.gov/pubmed/28757970
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc02402a
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