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Controllability of dynamic double helices: quantitative analysis of the inversion of a screw-sense preference upon complexation

We describe a quantitative analysis of the complexation-induced inversion of a screw-sense preference based on a conformationally dynamic double-helix structure in a macrocycle. The macrocycle is composed of two twisting units (terephthalamide), which are spaced by two strands (1,3-bis(phenylethynyl...

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Publicado en:Chem Sci
Main Authors: Katoono, Ryo, Kawai, Shunsuke, Fujiwara, Kenshu, Suzuki, Takanori
Formato: Artigo
Idioma:Inglês
Publicado: Royal Society of Chemistry 2015
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC5506618/
https://ncbi.nlm.nih.gov/pubmed/28757962
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc02614h
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