Operando X-ray absorption and EPR evidence for a single electron redox process in copper catalysis

An unprecedented single electron redox process in copper catalysis is confirmed using operando X-ray absorption and EPR spectroscopies. The oxidation state of the copper species in the interaction between Cu(ii) and a sulfinic acid at room temperature, and the accurate characterization of the formed...

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Bibliographic Details
Published in:Chem Sci
Main Authors: Lu, Qingquan, Zhang, Jian, Peng, Pan, Zhang, Guanghui, Huang, Zhiliang, Yi, Hong, Miller, Jeffrey T., Lei, Aiwen
Format: Artigo
Language:Inglês
Published: Royal Society of Chemistry 2015
Subjects:
Chemistry
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5502399/
https://ncbi.nlm.nih.gov/pubmed/28717490
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc00807g
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