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Thermodynamics of the Flexible Metal-Organic Framework Material MIL-53(Cr) From First Principles

We use first-principles density functional theory total energy and linear response phonon calculations to compute the Helmholtz and Gibbs free energy as a function of temperature, pressure, and cell volume in the flexible metal-organic framework material MIL-53(Cr) within the quasiharmonic approxima...

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Publicado en:J Phys Chem C Nanomater Interfaces
Autor principal: Cockayne, Eric
Formato: Artigo
Lenguaje:Inglês
Publicado: 2017
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC5497523/
https://ncbi.nlm.nih.gov/pubmed/28690713
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.jpcc.6b11692
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