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Cu metal embedded in oxidized matrix catalyst to promote CO(2) activation and CO dimerization for electrochemical reduction of CO(2)

We propose and validate with quantum mechanics methods a unique catalyst for electrochemical reduction of CO(2) (CO(2)RR) in which selectivity and activity of CO and C(2) products are both enhanced at the borders of oxidized and metallic surface regions. This Cu metal embedded in oxidized matrix (ME...

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Bibliographic Details
Published in:Proc Natl Acad Sci U S A
Main Authors: Xiao, Hai, Goddard, William A., Cheng, Tao, Liu, Yuanyue
Format: Artigo
Language:Inglês
Published: National Academy of Sciences 2017
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5495255/
https://ncbi.nlm.nih.gov/pubmed/28607069
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1702405114
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