Microsecond X-ray absorption spectroscopy identification of Co(I) intermediates in cobaloxime-catalyzed hydrogen evolution

Rational development of efficient photo-catalytic systems for hydrogen production requires understanding the catalytic mechanism and detailed information about the structure of intermediates in the catalytic cycle. We demonstrate how time-resolved X-ray absorption spectroscopy in the microsecond tim...

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Bibliographic Details
Published in:Chemistry
Main Authors: Smolentsev, Grigory, Cecconi, Bianca, Guda, Alexander, Chavarot-Kerlidou, Murielle, van Bokhoven, Jeroen A., Nachtegaal, Maarten, Artero, Vincent
Format: Artigo
Language:Inglês
Published: 2015
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Article
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC5493984/
https://ncbi.nlm.nih.gov/pubmed/26388205
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201502900
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