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Stable porphyrin Zr and Hf metal–organic frameworks featuring 2.5 nm cages: high surface areas, SCSC transformations and catalyses

Two isostructural porphyrin Zr and Hf metal–organic frameworks (FJI-H6 and FJI-H7) are rationally synthesized, and are constructed from 2.5 nm cubic cages. Notably, they both possess high water and chemical stability and can undergo single-crystal to single-crystal transformations to embed Cu(2+) io...

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Dettagli Bibliografici
Pubblicato in:Chem Sci
Autori principali: Zheng, Jun, Wu, Mingyan, Jiang, Feilong, Su, Weiping, Hong, Maochun
Natura: Artigo
Lingua:Inglês
Pubblicazione: Royal Society of Chemistry 2015
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC5492870/
https://ncbi.nlm.nih.gov/pubmed/28706707
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc00213c
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