Electron Spin Relaxation and Biochemical Characterization of the Hydrogenase Maturase HydF: Insights into [2Fe-2S] and [4Fe-4S] Cluster Communication and Hydrogenase Activation

[Image: see text] Nature utilizes [FeFe]-hydrogenase enzymes to catalyze the interconversion between H(2) and protons and electrons. Catalysis occurs at the H-cluster, a carbon monoxide-, cyanide-, and dithiomethylamine-coordinated 2Fe subcluster bridged via a cysteine to a [4Fe-4S] cluster. Biosynt...

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Vydáno v:Biochemistry
Hlavní autoři: Shepard, Eric M., Byer, Amanda S., Aggarwal, Priyanka, Betz, Jeremiah N., Scott, Anna G., Shisler, Krista A., Usselman, Robert J., Eaton, Gareth R., Eaton, Sandra S., Broderick, Joan B.
Médium: Artigo
Jazyk:Inglês
Vydáno: American Chemical Society 2017
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5490485/
https://ncbi.nlm.nih.gov/pubmed/28525271
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.biochem.7b00169
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