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A supramolecular strategy for tuning the energy level of naphthalenediimide: Promoted formation of radical anions with extraordinary stability

We report a supramolecular strategy to promote and stabilize the formation of naphthalenediimide (NDI) radical anions. The LUMO and HOMO energy of NDI are lowered significantly by introducing cucurbit[7]uril (CB[7]) to each side of a designed NDI molecule through supramolecular complexation. This pr...

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Detalles Bibliográficos
Publicado en:Chem Sci
Main Authors: Song, Qiao, Li, Fei, Wang, Zhiqiang, Zhang, Xi
Formato: Artigo
Idioma:Inglês
Publicado: Royal Society of Chemistry 2015
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC5490429/
https://ncbi.nlm.nih.gov/pubmed/28706698
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc00862j
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