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Unexpected effect of catalyst concentration on photochemical CO(2) reduction by trans(Cl)–Ru(bpy)(CO)(2)Cl(2): new mechanistic insight into the CO/HCOO(–) selectivity
Photochemical CO(2) reduction catalysed by trans(Cl)–Ru(bpy)(CO)(2)Cl(2) (bpy = 2,2′-bipyridine) efficiently produces carbon monoxide (CO) and formate (HCOO(–)) in N,N-dimethylacetamide (DMA)/water containing [Ru(bpy)(3)](2+) as a photosensitizer and 1-benzyl-1,4-dihydronicotinamide (BNAH) as an ele...
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| Publicat a: | Chem Sci |
|---|---|
| Autors principals: | , , , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
Royal Society of Chemistry
2015
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5490049/ https://ncbi.nlm.nih.gov/pubmed/28706681 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc00199d |
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