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Ultrafast Independent N−H and N−C Bond Deformation Investigated with Resonant Inelastic X‐Ray Scattering

The femtosecond excited‐state dynamics following resonant photoexcitation enable the selective deformation of N−H and N−C chemical bonds in 2‐thiopyridone in aqueous solution with optical or X‐ray pulses. In combination with multiconfigurational quantum‐chemical calculations, the orbital‐specific el...

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Pubblicato in:Angew Chem Int Ed Engl
Autori principali: Eckert, Sebastian, Norell, Jesper, Miedema, Piter S., Beye, Martin, Fondell, Mattis, Quevedo, Wilson, Kennedy, Brian, Hantschmann, Markus, Pietzsch, Annette, Van Kuiken, Benjamin E., Ross, Matthew, Minitti, Michael P., Moeller, Stefan P., Schlotter, William F., Khalil, Munira, Odelius, Michael, Föhlisch, Alexander
Natura: Artigo
Lingua:Inglês
Pubblicazione: John Wiley and Sons Inc. 2017
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC5485001/
https://ncbi.nlm.nih.gov/pubmed/28374523
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201700239
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