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Synthesis and enzymatic ketonization of the 5-(halo)-2-hydroxymuconates and 5-(halo)-2-hydroxy-2,4-pentadienoates

5-Halo-2-hydroxymuconates and 5-halo-2-hydroxy-2,4-pentadienoates are stable dienols that are proposed intermediates in bacterial meta-fission pathways for the degradation of halogenated aromatic compounds. The presence of the halogen raises questions about how the bulk and/or electronegativity of t...

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Veröffentlicht in:Beilstein J Org Chem
Hauptverfasser: Stack, Tyler M M, Jr., William H Johnson, Whitman, Christian P
Format: Artigo
Sprache:Inglês
Veröffentlicht: Beilstein-Institut 2017
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Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5480330/
https://ncbi.nlm.nih.gov/pubmed/28684981
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3762/bjoc.13.101
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