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Enhanced intersystem crossing in core-twisted aromatics
We describe the design, bottom-up synthesis and X-ray single crystal structure of systematically twisted aromatics 1c and 2d for efficient intersystem crossing. Steric congestion at the cove region creates a nonplanar geometry that induces a significant yield of triplet excited states in the electro...
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| 出版年: | Chem Sci |
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| 主要な著者: | , , , |
| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
Royal Society of Chemistry
2017
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| 主題: | |
| オンライン･アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5477835/ https://ncbi.nlm.nih.gov/pubmed/28694952 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc05126j |
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