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Spin-crossover and high-spin iron(ii) complexes as chemical shift (19)F magnetic resonance thermometers

The potential utility of paramagnetic transition metal complexes as chemical shift (19)F magnetic resonance (MR) thermometers is demonstrated. Further, spin-crossover Fe(II) complexes are shown to provide much higher temperature sensitivity than do the high-spin analogues, owing to the variation of...

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Publié dans:Chem Sci
Auteurs principaux: Thorarinsdottir, Agnes E., Gaudette, Alexandra I., Harris, T. David
Format: Artigo
Langue:Inglês
Publié: Royal Society of Chemistry 2017
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Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC5477811/
https://ncbi.nlm.nih.gov/pubmed/28694955
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc04287b
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