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β‐Octabromo‐ and β‐Octakis(trifluoromethyl)isocorroles: New Sterically Constrained Macrocyclic Ligands

Presented herein is a study of the acid‐induced demetalation of two sterically hindered copper corroles, Cu β‐octabromo‐meso‐triphenylcorrole (Cu[Br(8)TPC]) and β‐octakis(trifluoromethyl)‐meso‐tris(p‐methoxyphenyl)corrole (Cu[(CF(3))(8)TpOMePC]). Unlike reductive demetalation, which affords the free...

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Detalhes bibliográficos
Publicado no:ChemistryOpen
Main Authors: Thomas, Kolle E., Beavers, Christine M., Gagnon, Kevin J., Ghosh, Abhik
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5474668/
https://ncbi.nlm.nih.gov/pubmed/28638773
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/open.201700035
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