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Spin‐Forbidden Branching in the Mechanism of the Intrinsic Haber–Weiss Reaction

The mechanism of the O(2) (⋅−) and H(2)O(2) reaction (Haber–Weiss) under solvent‐free conditions has been characterized at the DFT and CCSD(T) level of theory to account for the ease of this reaction in the gas phase and the formation of two different set of products (Blanksby et al., Angew. Chem. I...

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Vydáno v:ChemistryOpen
Hlavní autoři: Leitão, Ezequiel F. V., Ventura, Elizete, de Souza, Miguel A. F., Riveros, José M., do Monte, Silmar A.
Médium: Artigo
Jazyk:Inglês
Vydáno: John Wiley and Sons Inc. 2017
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC5474656/
https://ncbi.nlm.nih.gov/pubmed/28638768
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/open.201600169
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