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Stereocontrolled semi-syntheses of deguelin and tephrosin
We describe stereocontrolled semi-syntheses of deguelin and tephrosin, anti-cancer rotenoids isolated from Tephrosia vogelii. Firstly, we present a new two-step transformation of rotenone into rot-2′-enonic acid via a zinc-mediated ring opening of rotenone hydrobromide. Secondly, following conversio...
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| Publicado no: | Org Biomol Chem |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2017
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5471929/ https://ncbi.nlm.nih.gov/pubmed/28134391 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6ob02659a |
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