A new example of intra­molecular C—H⋯Ni anagostic inter­actions: synthesis, crystal structure and Hirshfeld analysis of cis-bis­[4-methyl-2-(1,2,3,4-tetra­hydro­naphthalen-1-yl­idene)hydrazinecarbo­thio­amidato-κ(2) N (1),S]nickel(II) di­methyl­formamide monosolvate

The reaction of Ni(II) acetate tetra­hydrate with 4-methyl-2-(1,2,3,4-tetra­hydro­naphthalen-1-yl­idene)hydrazinecarbo­thio­amide in a 2:1 molar ratio and recrystallization from di­methyl­formamide yielded the title compound, [Ni(C(12)H(14)N(3)S)(2)]·C(3)H(7)NO. The ligands act as monoanionic κ(2) N...

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Detalhes bibliográficos
Publicado no:Acta Crystallogr E Crystallogr Commun
Main Authors: de Oliveira, Adriano Bof, Beck, Johannes, Mellone, Sônia Elizabeth Brown S., Daniels, Jörg
Formato: Artigo
Idioma:Inglês
Publicado em: International Union of Crystallography 2017
Assuntos:
Research Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5458310/
https://ncbi.nlm.nih.gov/pubmed/28638645
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1107/S2056989017007198
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