Communication: Direct evidence for sequential dissociation of gas-phase Fe(CO)(5) via a singlet pathway upon excitation at 266 nm

We prove the hitherto hypothesized sequential dissociation of Fe(CO)(5) in the gas phase upon photoexcitation at 266 nm via a singlet pathway with time-resolved valence and core-level photoelectron spectroscopy with an x-ray free-electron laser. Valence photoelectron spectra are used to identify fre...

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Udgivet i:J Chem Phys
Main Authors: Wernet, Ph., Leitner, T., Josefsson, I., Mazza, T., Miedema, P. S., Schröder, H., Beye, M., Kunnus, K., Schreck, S., Radcliffe, P., Düsterer, S., Meyer, M., Odelius, M., Föhlisch, A.
Format: Artigo
Sprog:Inglês
Udgivet: AIP Publishing LLC 2017
Fag:
Communications
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5457291/
https://ncbi.nlm.nih.gov/pubmed/28595420
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1063/1.4984774
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