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Preparation and Chemical Properties of π-Conjugated Polymers Containing Indigo Unit in the Main Chain

π-Conjugated polymers based on indigo unit were prepared. Dehalogenative polycondensation of N-hexyl-6,6′-dibromoindigo with a zerovalent nickel complex gave a homopolymer, P(HexI), in 77% yield. Copolymer of N-hexyl-indigo and pyridine, P(HexI-Py), was also prepared in 50% yield. P(HexI) showed goo...

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Detalhes bibliográficos
Publicado no:Materials (Basel)
Main Authors: Fukumoto, Hiroki, Nakajima, Hisashi, Kojima, Takahiro, Yamamoto, Takakazu
Formato: Artigo
Idioma:Inglês
Publicado em: MDPI 2014
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5453285/
https://ncbi.nlm.nih.gov/pubmed/28788554
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3390/ma7032030
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