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Adsorption of atmospheric gases on cementite [Formula: see text] surfaces

We study the adsorption of a series of small molecules on the nonstoichiometric {010} surface of cementite (θ-Fe(3)C) by means of first-principles calculations. We find that CO, N(2), H(2)O, and CH(4) prefer to adsorb over iron atoms in an atop configuration. O(2), CO(2), and the OH radical prefer a...

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Bibliografische gegevens
Gepubliceerd in:J Chem Phys
Hoofdauteurs: Muñoz Ramo, David, Jenkins, Stephen J.
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: AIP Publishing LLC 2017
Onderwerpen:
Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5449272/
https://ncbi.nlm.nih.gov/pubmed/28571338
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1063/1.4984036
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