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Epidithiodiketopiperazines: Strain-Promoted Thiol-Mediated Cellular Uptake at the Highest Tension

[Image: see text] The disulfide dihedral angle in epidithiodiketopiperazines (ETPs) is near 0°. Application of this highest possible ring tension to strain-promoted thiol-mediated uptake results in efficient delivery to the cytosol and nucleus. Compared to the previous best asparagusic acid (AspA),...

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Publicat a:ACS Cent Sci
Autors principals: Zong, Lili, Bartolami, Eline, Abegg, Daniel, Adibekian, Alexander, Sakai, Naomi, Matile, Stefan
Format: Artigo
Idioma:Inglês
Publicat: American Chemical Society 2017
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5445525/
https://ncbi.nlm.nih.gov/pubmed/28573207
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscentsci.7b00080
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