Semibatch monomer addition as a general method to tune and enhance the mechanics of polymer networks via loop-defect control

Controlling the molecular structure of amorphous cross-linked polymeric materials is a longstanding challenge. Herein, we disclose a general strategy for precise tuning of loop defects in covalent polymer gel networks. This “loop control” is achieved through a simple semibatch monomer addition proto...

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Publicado en:Proc Natl Acad Sci U S A
Autores principales: Gu, Yuwei, Kawamoto, Ken, Zhong, Mingjiang, Chen, Mao, Hore, Michael J. A., Jordan, Alex M., Korley, LaShanda T. J., Olsen, Bradley D., Johnson, Jeremiah A.
Formato: Artigo
Lenguaje:Inglês
Publicado: National Academy of Sciences 2017
Materias:
Physical Sciences
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC5441719/
https://ncbi.nlm.nih.gov/pubmed/28439017
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1620985114
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