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Silica-supported isolated gallium sites as highly active, selective and stable propane dehydrogenation catalysts

Single-site gallium centers on the surface of silica are prepared via grafting of [Ga(OSi(OtBu)(3))(3)(THF)] on SiO(2–700) followed by a thermolysis step. The resulting surface species corresponds to well-defined tetra-coordinate gallium single-sites, [([triple bond, length as m-dash]SiO)(3)Ga(XOSi[...

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Publicat a:Chem Sci
Autors principals: Searles, Keith, Siddiqi, Georges, Safonova, Olga V., Copéret, Christophe
Format: Artigo
Idioma:Inglês
Publicat: Royal Society of Chemistry 2017
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Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC5433511/
https://ncbi.nlm.nih.gov/pubmed/28553501
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c6sc05178b
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