Adsorption and molecular siting of CO(2), water, and other gases in the superhydrophobic, flexible pores of FMOF-1 from experiment and simulation

FMOF-1 is a flexible, superhydrophobic metal–organic framework with a network of channels and side pockets decorated with –CF(3) groups. CO(2) adsorption isotherms measured between 278 and 313 K and up to 55 bar reveal a maximum uptake of ca. 6.16 mol kg(–1) (11.0 mol L(–1)) and unusual isotherm sha...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Moghadam, Peyman Z., Ivy, Joshua F., Arvapally, Ravi K., dos Santos, Antonio M., Pearson, John C., Zhang, Li, Tylianakis, Emmanouil, Ghosh, Pritha, Oswald, Iain W. H., Kaipa, Ushasree, Wang, Xiaoping, Wilson, Angela K., Snurr, Randall Q., Omary, Mohammad A.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2017
Assuntos:
Chemistry
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5433493/
https://ncbi.nlm.nih.gov/pubmed/28553541
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc00278e
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