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Reduction chemistry of neptunium cyclopentadienide complexes: from structure to understanding

Neptunium complexes in the formal oxidation states II, III, and IV supported by cyclopentadienyl ligands are explored, and significant differences between Np and U highlighted as a result. A series of neptunium(iii) cyclopentadienyl (Cp) complexes [Np(Cp)(3)], its bis-acetonitrile adduct [Np(Cp)(3)(...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Dutkiewicz, Michał S., Apostolidis, Christos, Walter, Olaf, Arnold, Polly L.
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5431675/
https://ncbi.nlm.nih.gov/pubmed/28553487
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c7sc00034k
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