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Enantioselective Dirhodium(II)-Catalyzed Cyclopropanations with Trimethylsilylethyl and Trichloroethyl Aryldiazoacetates

Highly functionalized cyclopropanecarboxylates were readily prepared by rhodium-catalyzed cyclopropanation of alkenes with aryldiazoacetates and styryldiazoaceates, in which the ester functionality is either trimethylsilylethyl (TMSE) or trichlorethyl (TCE). By having labile protecting groups on the...

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Detalhes bibliográficos
Publicado no:Tetrahedron
Main Authors: Negretti, Solymar, Cohen, Carolyn M., Chang, Jane J., Guptill, David M., Davies, Huw M. L.
Formato: Artigo
Idioma:Inglês
Publicado em: 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5426858/
https://ncbi.nlm.nih.gov/pubmed/28503000
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tet.2015.05.045
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